To transfer resources (brushes etc.) and the configuration you need the krita files from roaming and local.
Maybe the below thread gives you an idea.
Futhermore: There seems to be an issue in the current Krita version that causes errors if Krita can’t find a resource (e.g. a brush) in the file system which is listet in the database.
So, on top to the information in the linked thread:
- Stop Krita.
- Delete the Krita files in local and roaming on your new PC (like you did already)
- Copy the Krita related content of local and roaming from your old PC to your new PC:
- Go to the roaming folder
- Delete the file resourcecache.sqlite
- Start Krita
EDIT:
If your username for the new PC is different from your username of the old PC, you need to alter one file in your local folder.
Please read @AhabGreybeard reply about it.
No guarantee that this works, but maybe you have luck with it.